SYNTHESIS OF ISOPROPYLIDENE 5-ALKYL-5-HYDROXY-METHYLMALONATES AND THEIR APPLICATION TO THE PREPARATION OF 2-ALKYLACRYLIC ACIDS

Zhen-Chu Chen Department of Chemistry, Zhejiang University at Xixi Campus, Hangzhou, 310028, People's Republic of China

Jing-Hua Li College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China

Wei-Ke Su College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China

Abstract

Hydroxymethylated derivatives of isopropylidene 5-alkyl- malonates 3 were synthesized, via which 2-alkylacrylic acids 4 were prepared using isopropylidene 5-alkylmalonates 1 as starting materials.

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SYNTHESIS OF ISOPROPYLIDENE 5-ALKYL-5-HYDROXY-METHYLMALONATES AND THEIR APPLICATION TO THE PREPARATION OF 2-ALKYLACRYLIC ACIDS

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SYNTHESIS OF ISOPROPYLIDENE 5-ALKYL-5-HYDROXY-METHYLMALONATES AND THEIR APPLICATION TO THE PREPARATION OF 2-ALKYLACRYLIC ACIDS

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