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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 10
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Original Articles

ONE-POT OXIDATION AND WITTIG OLEFINATION OF ALCOHOLS USING O-IODOXYBENZOIC ACID AND STABLE WITTIG YLIDE*

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Pages 1499-1506 | Received 04 Apr 2000, Published online: 02 Aug 2010
 

Abstract

Benylic, allylic, and propargylic alcohols, as well as diols, can be oxidized with o-iodoxybenzoic acid (IBX) in the presence of stabilized Wittig ylideCitation[1] to generate α,β-unsaturated ester in one pot. This is useful when the intermediate aldehydes are unstable and difficult to isolate.

*IICT communication no. 4369.

ACKNOWLEDGMENTS

One of the authors (AM) is thankful to CSIR, New Delhi, for awarding Research Fellowship.

Notes

*IICT communication no. 4369.

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