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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 10
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Original Articles

OXIDATIVE DEPROTECTION OF OXIMES USING PYRIDINIUM FLUOROCHROMATE AND HYDROGEN PEROXIDE

Nemai C. Ganguly Department of Chemistry, University of Kalyani, Kalyani, W.B., 741 235, India
,
Arun K. Sukai Department of Chemistry, University of Kalyani, Kalyani, W.B., 741 235, India
,
Sripada De Department of Chemistry, University of Kalyani, Kalyani, W.B., 741 235, India
&
Prithwiraj De Department of Chemistry, University of Kalyani, Kalyani, W.B., 741 235, India
Pages 1607-1612 | Received 15 May 2000, Published online: 02 Aug 2010
 
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Abstract

A simple convenient procedure of oxidative deoximation has been developed using pyridinium fluorochromate (PFC), in combination with 30% hydrogen peroxide. The method has been found to be effective for a wide range of aliphatic and aromatic oximes, and may be used for selective cleavage of aldoximes in the presence of ketoximes.

ACKNOWLEDGMENTS

One of the authors (AKS) is thankful to the University of Kalyani for a research fellowship.

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