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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 31, 2001 - Issue 13
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Original Articles

THE NOVEL SELECTIVE REDUCTION OF THE CARBON-CARBON TRIPLE BOND USING Pd(PPh3)4 AS A CATALYST

WenXin Gu Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China
,
XiaoChuan Chen Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China
,
XinFu Pan Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China
&
AnXin Wu Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, P.R. China
Pages 1983-1986 | Received 16 May 2000, Published online: 09 Nov 2006
 
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Abstract

A novel selective reduction system is reported in which compounds with terminal carbon-carbon triple bond and internal carbon-carbon triple bond were treated with NaBH4-Pd(PPh3)4 in basic conditions and only the terminal C-C triple bond was reduced.

ACKNOWLEDGMENT

We are grateful to the National Science Foundation of China for financial support.

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