DEHALOGENATION OF α-HALOCARBONYLS USING DECABORANE AS A TRANSFER HYDROGEN AGENT IN METHANOL

Seung Hwan Lee Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Yeon Joo Jung Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Young Jin Cho Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Choon-Ock Maing Yoon Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Han-Joon Hwang Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Cheol Min Yoon Graduate School of Biotechnology, Korea University, 1, 5-Ka, Anam-Dong, Sungbuk-Ku, Seoul, 136-701, S. Korea

Abstract

Decaborane reduces α-halocarbonyl compounds to the corresponding dehalogenated products in the presence of Pd/C in methanol at room temperature efficiently and chemoselectively.

ACKNOWLEDGMENTS

This workwas supported by Korea Research Foundation (KRF-99-2000).

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DEHALOGENATION OF α-HALOCARBONYLS USING DECABORANE AS A TRANSFER HYDROGEN AGENT IN METHANOL

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DEHALOGENATION OF α-HALOCARBONYLS USING DECABORANE AS A TRANSFER HYDROGEN AGENT IN METHANOL

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