INDIUM MEDIATED ALLYLATION OF NITRO GROUP ON NITROBENZENE DERIVATIVES IN AQUEOUS MEDIA

Kyung Ho Kang Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130-650, S. Korea

Kyung Il Choi Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130-650, S. Korea

Hun Yeong Koh Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130-650, S. Korea

Youseung Kim Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130-650, S. Korea

Bong Young Chung Department of Chemistry, Korea University, Seoul, 136-701, S. Korea

Yong Seo Cho Biochemicals Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul, 130-650, S. Korea

Abstract

Indium mediated allylation of nitro group was first achieved with four allyl bromides in aqueous media. Nitro- benzenes bearing 3- and/or 4-substituent(s) gave mainly N,N-diallylated (I or I′) and/or N,O-diallylated (II) products by Method A. Allylation of nitrobenzenes having 2- (and 5-) substituent(s) could be achieved only with crotyl bromide by Method B.

ACKNOWLEDGMENTS

This project was financially supported by the Korea Ministry of Science and Technology.

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INDIUM MEDIATED ALLYLATION OF NITRO GROUP ON NITROBENZENE DERIVATIVES IN AQUEOUS MEDIA

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INDIUM MEDIATED ALLYLATION OF NITRO GROUP ON NITROBENZENE DERIVATIVES IN AQUEOUS MEDIA

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