ULTRASOUND PROMOTED SYNTHESIS OF β-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL

Phil Ho Lee Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea

Keukchan Bang Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea

Kooyeon Lee Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea

Sun-young Sung Department of Chemistry, Kangwon National University, Chunchon, 200-701, South Korea

Sukbok Chang Department of Chemistry, Ewha Womans University, Seoul, 120-750, South Korea

Abstract

Ultrasound promoted Reformatsky reaction by the reaction of aldehydes or ketone with ethyl bromoacetate in the presence of indium metal afforded β-hydroxyesters in good to excellent yields under mild conditions.

ACKNOWLEDGMENTS

This work was supported by Korea Research Foundation Grant (KRF-99-005-D00048). The gas chromatograms were provided by GC facility, supported by Research Center for Advanced Mineral Aggregate Composite Products.

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ULTRASOUND PROMOTED SYNTHESIS OF β-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL

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ULTRASOUND PROMOTED SYNTHESIS OF β-HYDROXYESTERS BY REFORMATSKY REACTION USING INDIUM METAL

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