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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 2
369
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Original Articles

ELECTROCHEMICAL BEHAVIOUR OF HYDRAZONATES IN PROTIC AND APROTIC MEDIUM

, &
Pages 225-233 | Received 02 May 2000, Published online: 16 Aug 2006
 

ABSTRACT

Cathodic reduction of several hydrazonates of a typical structure (Scheme ) has been investigated by cyclic voltammetry and controlled potential electrolysis at mercury electrode in aprotic solvent. Quantitative results for preparative electrolysis run in the presence of a protic donor show the occurrence of reductive cleavage of the median N–N bond leading to the formation of imines and iminoethers in good yields.

ACKNOWLEDGMENT

Authors wish to thank SERST (Lab-CH02) for financial support and assistance.

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