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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 4
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Original Articles

MILD, EFFICIENT, AND CONVENIENT CONVERSION OF OXIRANES TO THIIRANES WITH AMMONIUM THIOCYANATE AND THIOUREA IN THE PRESENCE OF CERIUM(IV) POLYOXOMETALLATE

V. Mirkhani Department of Chemistry, University of Isfahan, Isfahan, 81744, Iran
,
S. Tangestaninejad Department of Chemistry, University of Isfahan, Isfahan, 81744, Iran
&
L. Alipanah Department of Chemistry, University of Isfahan, Isfahan, 81744, Iran
Pages 621-626 | Received 27 Dec 2000, Published online: 16 Aug 2006
 
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ABSTRACT

Selective conversion of various oxiranes to the corresponding thiiranes in the presence of ammonium thiocyanate and thiourea can be effectively carried out by ammonium decatungestocerate(IV) icosahydrate, (NH4)8[CeW10O36]ċ20H2O.

ACKNOWLEDGMENT

We thank the financial support for this work by the Isfahan University Research Council and Prof. I. Mohammadpoor-Baltork for his expert assistance.

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