INDIUM-MEDIATED ALLYLATION OF ACYL CYANIDES IN AQUEOUS MEDIA: A CONVENIENT SYNTHESIS OF β,γ-UNSATURATED KETONES

Byung Woo Yoo Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea

Kwang Hyun Choi Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea

Sung Jae Lee Department of Chemistry, Korea University, Chochiwon, Chungnam, 339-700, Korea

Ghil Soo Nam Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea

Kwan Young Chang Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea

Sung Hoon Kim Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea

Joong Hyup Kim Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, 130-650, Korea

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ABSTRACT

The indium-mediated allylation reaction of acyl cyanides with allyl halides in aqueous media afforded a variety of β,γ-unsaturated ketones in moderate to good yields under mild and neutral conditions.

ACKNOWLEDGMENTS

This work was financially supported by Korea Institute of Science and Technology (2E16800) and partially by Korea University.

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INDIUM-MEDIATED ALLYLATION OF ACYL CYANIDES IN AQUEOUS MEDIA: A CONVENIENT SYNTHESIS OF β,γ-UNSATURATED KETONES

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INDIUM-MEDIATED ALLYLATION OF ACYL CYANIDES IN AQUEOUS MEDIA: A CONVENIENT SYNTHESIS OF β,γ-UNSATURATED KETONES

ABSTRACT

ACKNOWLEDGMENTS

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