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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 8
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Original Articles

FREE RADICAL REACTION OF SODIUM ARENESULFINATES WITH ACETYLENES: NEW REGIO- AND STEREOSELECTIVE PREPARATION OF (E)-β-(PHENYLSELENO)VINYL SULFONES

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Pages 1243-1249 | Received 21 Jan 2001, Published online: 16 Aug 2006
 

ABSTRACT

1Free radical reaction of terminal acetylenes with sodium arenesulfinates and diphenyl diselenide in aqueous acetic acid afforded high yields of the regio- and stereoselective (E)-β-(phenylseleno)vinyl sulfones.

ACKNOWLEDGMENT

This work was supported by the Doctoral Program Foundation of National Education Ministry of China and also by the Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

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