HYPERVALENT IODINE IN SYNTHESIS. 78. DIRECT α-HYDROXYLATION OF KETONES USING [HYDROXY(TOSYLOXY)- IODO]BENZENE IN DIMETHYL SULFOXIDE–WATER: Synthetic Communications: Vol 32, No 12

Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 32, 2002 - Issue 12

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ABSTRACT

Ketones react with [hydroxy(tosyloxy)iodo]benzene in dimethyl sulfoxide–water to afford α-hydroxyketones under neutral conditions and in good yields.

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HYPERVALENT IODINE IN SYNTHESIS. 78. DIRECT α-HYDROXYLATION OF KETONES USING [HYDROXY(TOSYLOXY)- IODO]BENZENE IN DIMETHYL SULFOXIDE–WATER

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HYPERVALENT IODINE IN SYNTHESIS. 78. DIRECT α-HYDROXYLATION OF KETONES USING [HYDROXY(TOSYLOXY)- IODO]BENZENE IN DIMETHYL SULFOXIDE–WATER

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