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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 13
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Original Articles

ACID-MEDIATED, CHROMIUM-CATALYZED ALLYLATION OF ALDEHYDES

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Pages 1923-1928 | Received 23 Jun 2001, Published online: 16 Aug 2006
 

ABSTRACT

Allyl bromides are efficiently coupled with aryl and aliphatic aldehydes in the presence of manganese metal, collidine hydrochloride, bis(diisopropylphosphino)ethane and chromium dichloride. Homoallylic alcohols are isolated in good to excellent yields directly from the reaction mixture.

ACKNOWLEDGMENTS

This work was supported by The University of Alabama and an Aid to Education Grant from the DuPont Corporation.

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