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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 14
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Original Articles

REDUCTION OF CARBONYL COMPOUNDS TO THE CORRESPONDING ALCOHOLS WITH ISOPROPANOL ON DEHYDRATED ALUMINA UNDER MICROWAVE IRRADIATION

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Pages 2255-2260 | Received 22 May 2001, Published online: 18 Oct 2011
 

ABSTRACT

The reduction of different types of aldehydes and ketones were performed in the presence of isopropylalcohol (as solvent and hydride source) under microwave irradiation. It is proved that dehydrated Woelm chromatographic alumina supported KOH catalyses these transformations. Regioselectivity was observed in the reduction of cinnamaldehyde and chemoselectivity was observed in the reduction of carbonyl in the presence of nitro group.

ACKNOWLEDGMENT

We would like to acknowledge the partial support of this work by Shahid Chamran Ahvaz University Research Council.

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