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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 32, 2002 - Issue 19
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Original Articles

La(O-i-Pr)3 CATALYZED THREE-COMPONENT CONDENSATION REACTION: A CONVENIENT SYNTHESIS OF N,N-DIALKYL-α-CYANOAMINES

, , &
Pages 2973-2978 | Received 18 Sep 2001, Published online: 16 Aug 2006
 

ABSTRACT

In the presence of 10 mol% of La(O-i-Pr)3, a three-component condensation reaction of aldehyde, secondary amine and trimethylsilylcyanide proceeded smoothly to afford N,N-dialkyl-α-cyanoamine in good yield.

ACKNOWLEDGMENTS

We thank the National Natural Science Foundation of China and the State Key Project of Basic Research (Project 973) (No. G2000048007) for their financial supports.

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