Indium Mediated Allylation of β-Chloro-/β-Alkoxy Vinylaldehyde: A Facile One Pot Synthesis of 1-Chloro-/1-Alkoxy Hexa-1,5-diene-3-ol Derivatives

Dipanjan Pan Department of Chemistry, Indian Institute of Technology, Kharagpur, India

Gandhi K. Kar Department of Chemistry, Indian Institute of Technology, Kharagpur, India

Jayanta K. Ray Department of Chemistry, Indian Institute of Technology, Kharagpur, India; Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, IndiaCorrespondence[email protected]

Abstract

Indium mediated allylation of β-chloro- or β-alkoxy vinylaldehydes in the presence of sodium iodide produce homoallylic alcohol derivatives (1-chloro-/1-alkoxy hexa-1,5-diene-3-ol derivatives) in good yields.

Acknowledgment

Financial support from CSIR, New Delhi is gratefully acknowledged.

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Indium Mediated Allylation of β-Chloro-/β-Alkoxy Vinylaldehyde: A Facile One Pot Synthesis of 1-Chloro-/1-Alkoxy Hexa-1,5-diene-3-ol Derivatives

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Indium Mediated Allylation of β-Chloro-/β-Alkoxy Vinylaldehyde: A Facile One Pot Synthesis of 1-Chloro-/1-Alkoxy Hexa-1,5-diene-3-ol Derivatives

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