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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 2
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Original Articles

1,3-Dipolar Cycloaddition Reaction of C-Acetyl-N-arylnitrilimines with Selected Aliphatic Benzoylhydrazones

Pages 243-251 | Received 10 Dec 2001, Published online: 21 Aug 2006
 

Abstract

C-Acetyl-N-arylnitrilimines (2) react with acetaldehyde, alkanone, and cycloalkanone benzoylhydrazones (3) to give the cycloaddition products 4-benzoylamino-4,5-dihydro-1,2,4-triazoles (415) rather than the tetrazine cyclocondensation products (16).

Acknowledgment

The author wishes to thank Dr. W. Schrader, Max-Planck Institut fuer Kohlenforschung, Muelheim, Germany, for obtaining the mass spectra.

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