Facile Synthesis of 3-Thiomethyl-2-isozoline Derivatives: New Sulfide Formation from Epoxide Containing Isoxazolines via Retro-Aldol Type Reaction

Hyoung Cheul Kim Department of Chemistry, Yonsei University, Seodaemun-gu, Seoul, Korea

Su Yeon Jo Bioorganic Science Division, Korea Research Institute of Chemical Technology, Yusong, Taejon, Korea

Dong Ju Jeon Bioorganic Science Division, Korea Research Institute of Chemical Technology, Yusong, Taejon, Korea

Chul-Ho Jun Department of Chemistry, Yonsei University, Seodaemun-gu, Seoul, Korea

Hyoung Rae Kim Bioorganic Science Division, Korea Research Institute of Chemical Technology, Yusong, Taejon, KoreaCorrespondence[email protected]

Abstract

Various 3-thiomethyl-2-isoxazolines which were not easily available were prepared from 3-(2,2-dimethyloxiran-1-yl)isoxazolines by using sodium thiolates via retro-Aldol type reaction in good yields.

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Facile Synthesis of 3-Thiomethyl-2-isozoline Derivatives: New Sulfide Formation from Epoxide Containing Isoxazolines via Retro-Aldol Type Reaction

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Facile Synthesis of 3-Thiomethyl-2-isozoline Derivatives: New Sulfide Formation from Epoxide Containing Isoxazolines via Retro-Aldol Type Reaction

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