Convenient One Pot Synthesis of Phosphonites and H-Phosphinates

Imre Petneházy Department of Organic Chemical Technology, Budapest University of Technology and Economics, Budapest, HungaryCorrespondence[email protected]

Zsuzsa M. Jászay Organic Chemical Technological Research Group of the Hungarian Academy of Sciences, Budapest, Hungary

Andrea Szabó Department of Organic Chemical Technology, Budapest University of Technology and Economics, Budapest, Hungary

Kinga Everaert Department of Organic Chemical Technology, Budapest University of Technology and Economics, Budapest, Hungary

Abstract

A convenient and simple one-pot method is described for the synthesis of phosphonites [RP(OEt)₂, 1] and H-phosphinates [HP(O)R(OEt), 2] from triethyl phosphite and appropriate Grignard reagents.

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Acknowledgments

Support from the Hungarian National Research Foundation (OTKA T026478) and the Ministry of Education (TÉT-Balaton F19/98) is acknowledged.

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Convenient One Pot Synthesis of Phosphonites and H-Phosphinates

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Convenient One Pot Synthesis of Phosphonites and H-Phosphinates

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