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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 11
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Original Articles

Synthesis of New bis-Iminocoumarins by Schmidt Reaction Catalyzed by Ion-Exchange Resins

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Pages 1821-1828 | Received 20 Jul 2002, Published online: 17 Aug 2006
 

Abstract

A new synthetic route to bis-iminocoumarins is proposed which involves the synthesis of iminocoumarins from reaction of 2-hydroxybenzaldehydes with arylacetonitriles and their coupling with aromatic diamines. Ion-exchange resins were used as catalysts in both steps of this synthesis. The reaction parameters were varied and obtained using Amberlyst 15 resin in cyclohexane at 80°C.

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