In/InCl₃-Mediated 1,2-Addition of Allyl Group to α,β-Unsaturated Carbonyl Compounds

Hye Yeon Kim Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, Korea; Department of Chemistry, Hanyang University, Sungdong-Gu, Seoul, Korea

Kyung Il Choi Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, Korea

Ae Nim Pae Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, Korea

Hun Yeong Koh Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, Korea

Jung Hoon Choi Department of Chemistry, Hanyang University, Sungdong-Gu, Seoul, Korea

Yong Seo Cho Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul, KoreaCorrespondence[email protected]

Abstract

In/InC1₃-mediated addition of allyl iodide to α,β-unsaturated carbonyl compounds gave moderate to high yields of 1,2-addition products. The reactions covered acylic and cyclic α,β-unsaturated carbonyl compounds. Indium trichloride was effective for these Barbier-type allylation reactions.

Keywords:

Acknowledgment

This project was financially supported by the Korea Ministry of Science and Technology (Critical technology 21) and Korea Institute of Science and Technology.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

In/InCl₃-Mediated 1,2-Addition of Allyl Group to α,β-Unsaturated Carbonyl Compounds

Information for

Open access

Opportunities

Help and information

In/InCl3-Mediated 1,2-Addition of Allyl Group to α,β-Unsaturated Carbonyl Compounds

Abstract

Acknowledgment

Reprints and Corporate Permissions

Academic Permissions

Related research

To cite this article:

Download citation

Information for

Open access

Opportunities

Help and information

Keep up to date

Your download is now in progress and you may close this window

Login or register to access this feature

In/InCl₃-Mediated 1,2-Addition of Allyl Group to α,β-Unsaturated Carbonyl Compounds