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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 12
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Original Articles

ortho-(Substituted Silyl)phenylsydnones via a Novel Sydnone to Phenyl Ring, Lithiation-Induced Silicon Migration

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Pages 2061-2067 | Received 03 Oct 2002, Published online: 17 Aug 2006
 

Abstract

3-(2-Bromophenyl)sydnone (5) reacts with LDA then substituted chlorosilanes to form the corresponding 4-silylsydnones 6, which rearrange to the novel ortho-silylphenylsydnones 8 on treatment with n-butyllithium.

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