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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 13
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Original Articles

Conversion of Thiiranes to β-Chlorothioacetates Catalyzed with CoCl2

N. Iranpoor Chemistry Department, College of Sciences, Shiraz University, Shiraz, IranCorrespondence[email protected]
,
H. Firouzabadi Chemistry Department, College of Sciences, Shiraz University, Shiraz, IranCorrespondence[email protected]
&
A. A. Jafari Chemistry Department, College of Sciences, Shiraz University, Shiraz, Iran
Pages 2321-2327 | Received 16 Oct 2002, Published online: 17 Aug 2006
 
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Abstract

Cobalt (II) chloride catalyzes the ring opening of thiiranes with acetyl chloride to produce vicinal chlorothioesters in good yields.

Acknowledgment

The authors appreciate the Research Council of Shiraz University for partial support of this work.

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Related Research Data

A Sequential One-Pot Synthesis of Functionalized Esters and Thioesters through a Ring-Opening Acylation of Cyclic Ethers and Thioethers
Source: Wiley
N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes†
Source: Wiley

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