Abstract
Synth. Commun. 2003, 33, 2757
Lewis Acid-Catalyzed Cyclotrimerization of Methyl 3-Acetylazulene-1-Carboxylate in Alcohols
Satoko Yamashiro1 and Kimiaki Imafuku2,*
1Department of Materials and Life Science, Graduate School of Science and Technology, Kumamoto University, Kurokami, Kumamoto, Japan
2Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami, Kumamoto, 860-8555, Japan
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Abstract
Synth. Commun. 2003, 33, 2763
A New and Efficient Method for the Synthesis of 2,2′-Dibromo-1,1′-Binaphthyl Under Microwave Irradiation
Li-wen Xu, Fu-wei Li, Chun-gu Xia,* and Wei Sun
State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, 73000, P.R. China
A very simple and efficient method to prepare 2,2′-dibromo-1,1′-binaphthyl via two-step procedure from β-naphthol in good yield under microwave irradiation is described.
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Abstract
Synth. Commun. 2003, 33, 2769
Convenient Preparation of 3,6-Dialkyl-1,6-dihydro-s-tetrazines
Yaquan Sun, Weixiao Hu,* and Qing Yuan
Institute of Pharmaceutical Engineering, Zhejiang University of Technology, Hangzhou 310014, P.R. China
Using Pd/C in place of PtO2 as catalyst, a convenient synthesis of 1,6-dihydro-s-tetrazine from aledehyde has presented. This method is accessible.
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Abstract
Synth. Commun. 2003, 33, 2777
Free Radical Reaction of Dialkyl Phosphites and Organic Dichalcogenides: A New Facile and Convenient Preparation of Arylselenophosphates
Qing Xu,1,2 Chun-Gen Liang,1,2 and Xian Huang1,2,*
1Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou 310028,P.R. China
2Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P.R. China
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Abstract
Synth. Commun. 2003, 33, 2787
Highly Catalytic Enantioselective Epoxidation of Enones with Weak Base Bicarbonate and Hydrogen Peroxide
Chao-Shan Da,1 Jie Wei,1 Shou-Liang Dong,1 Zhuo-Qun Xin,1 Da-Xue Liu,1 Zhao-Qin Xu,1 and Rui Wang1,2,*
1Department of Biochemistry and Molecular Biology, School of Life Sciences, Lanzhou University, Lanzhou 730000, China
2State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
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Abstract
Synth. Commun. 2003, 33, 2793
Catalytic Asymmetric Oxidation of Alkyl Aryl Sulfides Mediated by a Series of Chiral N-Alkyl-1,2-diphenylaminoethanol/Titanium/Water Complexes
YunGui Peng,1 XiaoMing Feng,2,* Xin Cui,3 YaoZhong Jiang,3,* Michael C. K. Choi,4 and Albert S. C. Chan4
1The School of Chemistry and Chemical Engineering, Southwest Normal University, BeiBei, ChongQing 400715, China
2Sichuan Key Laboratory of Green Chemistry and Technology, College of Chemistry, Sichuan University, Chengdu 610064, China
3Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
4Open Laboratory of Chirotechnology and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China
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Abstract
Synth. Commun. 2003, 33, 2803
The Preparation of Butyrylated NAD+ Type of Biological Molecules
Ki-Jun Hwang,1,* Beom-Tae Kim,1 and Uh-Hyun Kim2
1Department of Chemistry, and Research Center of Bioactive Materials, College of Natural Science, and 2Department of Biochemistry, Medical School, Chonbuk National University, Dukjindong 664-14, Chonju, S. Korea 561-756
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Abstract
Synth. Commun. 2003, 33, 2811
A Mild and Efficient Method of Synthesis of a Series of New Multi-Dentate Ligands
Hui An Tang1,2,*, Sheng Yang,1 and Ru Dong Yang1
1Chemistry Department of TianShui Normal University, TianShui, Gansu, P.R. China; 2College of Chemistry and Chemical Engineering of LanZhou University, P.R. China
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Abstract
Synth. Commun. 2003, 33, 2817
Organic Reactions in Ionic Liquids: Alkylation of Meldrum's Acid
Ce Su,2 Zhen-Chu Chen,1,2,* and Qin-Guo Zheng3
1Ningbo Institute of Technology, Zhejiang University, Ningbo, 315104, P.R. China
2Department of Chemistry, Zhejiang University (Xi-Xi campus), Hangzhou, 310028, P.R. China
3Pharmaceutical Sciences Research Institute, Aston University, Aston Triangle, Birmingham B4 7ET, UK
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Abstract
Synth. Commun. 2003, 33, 2823
A Convenient Synthesis of 3,5-Diaryl-1,2,4-selenadiazoles
Xian Huang1,2,* and Jiangmin Chen1
1Department of Chemistry, Zhejiang University (Xixi Campus), No. 148, Tianmushan Road, Hangzhou, 310028, P.R. China
2State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P.R. China
3,5-Diaryl-1,2,4-selenadiazoles were prepared in high yields from primary selenoamides using poly[styrene(iodosodiacetate)] as oxidant. The polymer reagent could be regenerated and reused.
![](/cms/asset/17379aa5-de36-405e-8404-fd63f29fe470/lsyc_a_10354139_o_uc0010.gif)
Abstract
Synth. Commun. 2003, 33, 2829
Acetonyltriphenylphosphonium Bromide and its Polymer-Supported Analogues as Catalysts for the Protection of Carbonyl Compounds as Acetals or Thioacetals
Yung-Son Hon,1,2,* Chia-Fu Lee,1 Rong-Jiunn Chen,1 and Yi-Fen Huang1
1Department of Chemistry and Biochemistry, National Chung Cheng University, Chia-Yi, Taiwan 621, R.O.C.
2Institute of Chemistry, Academia Sinica, Nankang, Taipei, Taiwan 115, R.O.C.
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Abstract
Synth. Commun. 2003, 33, 2843
A Facile and Selective Synthesis of 2-Alkylamino-4(3H)-quinazolinones
Yi Liang, Ming-Wu Ding,* Zhao-Jie Liu, and Xiao-Peng Liu
Institute of Organic Synthesis, Central China Normal University, Wuhan, 430079, P.R. China
The carbodiimides 2, obtained from aza–Wittig reactions of iminophosphorane 1 with aromatic isocyanates, reacted with aliphatic primary amines to give mainly 2-alkylamino-4(3H)-quinazolinones 4 with unusual selectivity.
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Abstract
Synth. Commun. 2003, 33, 2849
Facile Synthesis of 2-Aroyl-3,5-diarylthiophene
Jin-Xian Wang,* Xiaoning Shi, Xiuqin Men, and Lianbiao Zhao
Institute of Chemistry, Department of Chemistry, Northwest Normal University, 805 An Ning Road (E.) Lanzhou, 730070, P.R. China
2-Aroyl-3,5-diarylthiophenes were prepared in very good yields by reaction of 2,4,6-triarylpyrylium salts or 2,4,6-triarylthiopyrylium salts with an aqeous solution of sodium sulfide and iodine at room temperature.
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Abstract
Synth. Commun. 2003, 33, 2857
Highly Diastereoselective Preparation of Cyclic Sulfates From Allyl and Homoallyl Alcohols via One-Pot Halocyclosulfations
Masahiro Inoue, Shinji Motomatsu, and Masahisa Nakada*
Department of Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku-ku, 169-8555, Tokyo, Japan
Diastereoselective electrophilic heteroatom cyclizations of the monosulfates of homoallyl and allyl alcohols are described.
![](/cms/asset/c1b24deb-443d-492b-8086-981435f65aea/lsyc_a_10354139_o_uc0014.gif)
Abstract
Synth. Commun. 2003, 33, 2867
Selenium-Linking Strategy for Traceless Solid-Phase Synthesis of Acrylamides
Shou-Ri Sheng,* Xing-Cong Wang, Xiao-Ling Liu, and Cai-Sheng Song
Department of Chemistry, Jiangxi Normal University, Nanchang, 330027, P.R. China
A novel polystyrene-supported β-selenopropionic acid has been developed and applied to simple and efficent synthesis of acrylamides.
![](/cms/asset/949063b4-2f74-4c3a-bca7-71484e9efbd9/lsyc_a_10354139_o_uc0015.gif)
Abstract
Synth. Commun. 2003, 33, 2873
Stereospecific Synthesis of trans-2,3-Diaryl Substituted 1-Aminocyclopropanecarboxylic Acid Derivatives
Guifa Su,1,2,3,* Hongtao Mu,2 Danming Za,2 Longmei Zeng,1 Carlos Cativiela,3 Robert P. Hammer,4 and Kaibei Yu5
1College of Chemistry and Chemical Engineering, Zhongshan University, Canton 510275, P.R. China
2Department of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, P.R. China
3Department of Organic Chemistry, ICMA, University of Zaragoza, Zaragoza 50009, Spain
4Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA
5Chengdu Analysis and Testing Center, Academia Sinica, Chengdu 610041, P.R. China
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Abstract
Synth. Commun. 2003, 33, 2885
One-Pot Preparation of Esters From Carboxylic Acids Using the PPh3–CCl3CN System
Doo Ok Jang,1,* Dae Hyan Cho,1 and Joong-Gon Kim2
1Department of Chemistry, Yonsei University, Wonju 220-710, Korea
2Biotechnology Division, Hanwha Chemical R & D Center, Taejon 305-345, Korea
A convenient one-pot process for preparing various esters from carboxylic acids using the Ph3P–CCl3CN has been developed. Racemic α-tocopherol, clofibrate, and flavoxate were prepared in high yields using this method.
![](/cms/asset/f681197f-b45f-4a87-b4f4-003a9b5acb8d/lsyc_a_10354139_o_uc0017.gif)
Abstract
Synth. Commun. 2003, 33, 2891
Solvent-Free Synthesis of 2-Furyl-5-aryloxyacetylamido-1,3,4-thiadiazoles Under Microwave Irradiation
Xicun Wang, Zheng Li,* Zhengjun Quan, Xinsheng Lu, and Ruhu Gou
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu, 730070, P.R. China
A practical solvent-free method for the preparation of 2-furyl-5-aryloxyacetylamido-1,3,4-thiadiazoles under microwave irradiation is described.
![](/cms/asset/c0663975-57ee-4d56-9a32-67c2345adf1f/lsyc_a_10354139_o_uc0018.gif)
Abstract
Synth. Commun. 2003, 33, 2899
An Improved Synthesis of N -Substituted-2-Nitroanilines
S. M. S. Chauhan,* Ram Singh, and Geetanjali
Department of Chemistry, University of Delhi, Delhi-110 007, India
The reaction of 2-chloronitrobenzene with substituted amines/anilines in the presence of DBU gives N-substituted-2-nitroanilines in >75–90% yield.
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Abstract
Synth. Commun. 2003, 33, 2907
Stereoselective Synthesis of (−)-Cytoxazone and (+)-5-Epi-Cytoxazone
A. Ravi Kumar, G. Bhaskar, A. Madhan, and B. Venkateswara Rao*
Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India
![](/cms/asset/bb508eb5-06b1-403f-ae75-f894f99b7fef/lsyc_a_10354139_o_uc0020.gif)
Abstract
Synth. Commun. 2003, 33, 2917
Iodination of Enol Acetates and 1,3-Diones Using N-Iodosaccharin
Darko Dolenc*
University of Ljubljana, Faculty of Chemistry and Chemical Technology, Aškerčeva, 5, 1000 Ljubljana, Slovenia
Iodination of enol acetates and 1,3-diones with N-iodosaccharin yielding the corresponding α-iodoketones and 2-iodo-1,3-diones is presented. Reactions are carried out at room temperature under neutral conditions and in short reaction times.
![](/cms/asset/5e6fd3e8-81c4-4fee-80ac-326875e97112/lsyc_a_10354139_o_uc0021.gif)
Abstract
Synth. Commun. 2003, 33, 2925
Trityl-Directed Regiospecific Synthesis of 2,3-Disubstituted Bioimidazoles
Pooja Chandana, Amit Nayyar, and Rahul Jain*
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research, S.A.S. Nagar, Punjab, India
We report an efficient trityl-directed regiospecific synthesis of 2,3-disubstituted-l-histdines and 2,3-disubstituted histamines starting from α-N-trifluoroacetyl-l-histidine methyl ester and α-N-trifluoroacetylhistamine respectively in five steps.
![](/cms/asset/80fa8ef7-bb10-4f22-bb57-f6e1b5610b3a/lsyc_a_10354139_o_uc0022.gif)