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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 16
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Original Articles

Free Radical Reaction of Dialkyl Phosphites and Organic Dichalcogenides: A New Facile and Convenient Preparation of Arylselenophosphates

Qing Xu Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, P.R. China; Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P.R. China
,
Chun-Gen Liang Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, P.R. China; Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P.R. China
&
Xian Huang Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou, P.R. China; Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P.R. China
Pages 2777-2785 | Received 05 Nov 2002, Published online: 19 Aug 2006
 
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Abstract

Azobisisobutyronitrile-initiated free radical reaction of dialkyl phosphites with diaryl diselenides afforded arylselenophosphates in high yields. Arylthiophosphates and aryltellurophosphates can also be synthesized by similar reaction of diaryl disulfides and diaryl ditellurides with dialkyl phosphites.

Acknowledgment

This work supported by the Natural Science Foundation of Zhejiang Province and also by the Doctoral Program Foundation of National Education Ministry of China.

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