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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 22
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Original Articles

Iodoform, a New Reagent in the Todd-Atherton Reaction

Grażyna Mielniczak Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Łódź, Poland
&
Dr. Andrzej Bopusiński Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Łódź, PolandCorrespondence[email protected]
Pages 3851-3859 | Received 08 Apr 2003, Published online: 19 Aug 2006
 
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Abstract

An innovative and convenient application of the iodoform (1) as the reagent in the synthesis of phosphoramidates via Todd-Atherton reaction is described. The full stereoselectivity of this transformation using a 4-methyl-1,3,2-dioxaphosphinane model system was demonstrated.

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Related Research Data

Synthesis of new organophosphorus compounds using the atherton–todd reaction as a versatile tool
Source: Wiley
Synthesis and bioactivity evaluation of new phenyl N,N′-phenylphosphorodiamidates
Source: Informa UK Limited
Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates
Source: Royal Society of Chemistry (RSC)
LiI/TBHP Mediated Oxidative Cross-Coupling of P(O)-H Compounds with Phenols and Various Nucleophiles: Direct Access to the Synthesis of Organophosphat
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Reinvestigation of the iodine-mediated phosphoramidation reaction of amines and P(OR)3 and its synthetic applications
Source: Royal Society of Chemistry (RSC)

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