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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 33, 2003 - Issue 24
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Original Articles

Synthesis of Fluorinated Epoxides Opening the Way to New Hybrid Fluorocarbon-Hydrocarbon Surfactants

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Pages 4321-4329 | Received 19 Jun 2003, Published online: 21 Aug 2006
 

Abstract

Two methods of epoxidation were investigated on a hybrid fluorocarbon-hydrocarbon olefin: RuCl3/bipyridine/NaIO4 and oxone/acetone. The best yield was obtained using the first method which was extended to the synthesis of new aromatic fluorinated epoxides with very good yields.

Acknowledgment

This research was supported by the European Contract of Research Training Network (“Fluorous Phase” HPRN CT 2000-00002) and the European Union (COST—Action “Fluorous Medium” D12/98/0012).

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