(Dichloroiodo)benzene—An Easily Available Reagent for Chloro‐ and Iodoalkoxylation, Iodohydroxylation, and Iodochlorination of Alkenes

M. S. Yusubov Department of Organic Chemistry, Tomsk Polytechnic University, Tomsk, 634034, Russia; Department of Chemistry, Siberian State Medical University, Tomsk, RussiaCorrespondence[email protected]

R. J. Yusubova Department of Organic Chemistry, Tomsk Polytechnic University, Tomsk, 634034, Russia

V. D. Filimonov Department of Organic Chemistry, Tomsk Polytechnic University, Tomsk, 634034, Russia

Ki‐Whan Chi Department of Chemistry, University of Ulsan, Ulsan, Republic of Korea

Abstract

A convenient synthesis of vicinal methoxychlorides, methoxyiodides, iodhydrines and iodocloride from alkenes using PhICl₂/CH₃OH, I₂/PhICl₂/CH₃OH, I₂/PhICl₂/CH₃CN/H₂O and I₂/PhICl₂/CH₂Cl₂ is described.

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Acknowledgment

We thank Russian Foundation for Fundamental Researches (grant N 00‐03‐32812a) and Ministry of Education (grant N E02‐5.0‐176) for the financial support of this work.

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(Dichloroiodo)benzene—An Easily Available Reagent for Chloro‐ and Iodoalkoxylation, Iodohydroxylation, and Iodochlorination of Alkenes

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(Dichloroiodo)benzene—An Easily Available Reagent for Chloro‐ and Iodoalkoxylation, Iodohydroxylation, and Iodochlorination of Alkenes

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