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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 12
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Original Articles

Novel Bromination Method for Anilines and Anisoles Using NH4Br/H2O2 in CH3COOH

K. V. V. Krishna Mohan Catalysis Group, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
N. Narender Catalysis Group, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
P. Srinivasu Catalysis Group, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
,
S. J. Kulkarni Catalysis Group, Indian Institute of Chemical Technology, Hyderabad, 500 007, IndiaCorrespondence[email protected]
&
K. V. Raghavan Catalysis Group, Indian Institute of Chemical Technology, Hyderabad, 500 007, India
Pages 2143-2152 | Received 03 Jan 2004, Published online: 17 Aug 2006
 
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Abstract

A simple, efficient, regioselective, environmentally safe, and economical method for the oxybromination of anilines and anisoles without catalyst is reported. The electrophilic substitution of bromine generated in situ from ammonium bromide as a bromine source and hydrogen peroxide as an oxidant for the first time.

#IICT Communication No. 01/X/07.

Acknowledgments

We are thankful to Department of Science and Technology, New Delhi for funding, DST, Project No.: SP/S1/H07/97. PS thanks to CSIR, New Delhi for the award of a Senior Research Fellowship.

Notes

#IICT Communication No. 01/X/07.

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