Stereoselective Synthesis of cis‐1‐Aryl‐2‐benzoyl‐3,3‐dicyanocyclopropanes in the Presence of KF·2H₂O

Zhongjiao Ren Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. ChinaCorrespondence[email protected]

Weiguo Cao Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, P.R. China

Weiyu Ding Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China

Yu Wang Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China

Lilin Wang Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China

Abstract

KF · 2H₂O was found to be a highly efficient base for synthesis of cis‐1,2‐cyclopropanes with arsonium salt and olefins. The advantages of the process are mild reaction condition, easy workup, excellent yields, and high stereoselectivity.

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Acknowledgment

Thanks are due to the National Natural Science Foundation of China for financial support.

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Stereoselective Synthesis of cis‐1‐Aryl‐2‐benzoyl‐3,3‐dicyanocyclopropanes in the Presence of KF·2H₂O

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Stereoselective Synthesis of cis‐1‐Aryl‐2‐benzoyl‐3,3‐dicyanocyclopropanes in the Presence of KF·2H2O

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Stereoselective Synthesis of cis‐1‐Aryl‐2‐benzoyl‐3,3‐dicyanocyclopropanes in the Presence of KF·2H₂O