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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 23
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Original Articles

Gallium Triiodide Catalyzed Organic Reaction: A Convenient Synthesis of α‐Amino Phosphonates

Peipei Sun College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing, 210097, ChinaCorrespondence[email protected]
,
Zhixin Hu College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing, 210097, China
&
Zhihao Huang College of Chemistry and Environmental Science, Nanjing Normal University, Nanjing, 210097, China
Pages 4293-4299 | Received 11 Jun 2004, Published online: 10 Jan 2011
 
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Abstract

In dichloromethane, the three‐component coupling reaction of carbonyl compounds, amines, and diethyl phosphite was catalyzed effectively by gallium triiodide that was generated in situ by the reaction of gallium metal and iodine to give the corresponding α‐amino phosphonates in good to excellent yields. The method was appropriate for both primary and secondary amines.

Acknowledgment

Financial support of this research from the Natural Science Foundation of the Education Department of Jiangsu province is gratefully acknowledged (Project 03KJD150109).

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