Solvent‐Free Stereoselective Synthesis of cis‐1‐Carbomethoxy‐2‐Aryl‐3,3‐Dicyanocyclopropanes by Grinding

Zhongjiao Ren Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. ChinaCorrespondence[email protected]

Weiguo Cao Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, P.R. China

Weiyu Ding Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China

Wen Shi Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China

Abstract

The novel route of high stereoselective synthesis of cis‐1‐carbomethoxy‐2‐aryl‐3,3‐dicyanocyclopropanes by grinding is described. This process is simple, efficient, and environmentally benign.

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Acknowledgment

Thanks are due to the National Natural Science Foundation of China for financial support.

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Solvent‐Free Stereoselective Synthesis of cis‐1‐Carbomethoxy‐2‐Aryl‐3,3‐Dicyanocyclopropanes by Grinding

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Solvent‐Free Stereoselective Synthesis of cis‐1‐Carbomethoxy‐2‐Aryl‐3,3‐Dicyanocyclopropanes by Grinding

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