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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 11
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Original Articles

A Facile Approach for New Dibenzo [b,f][1,5] Diazocinones

, , &
Pages 1493-1500 | Received 27 Jan 2005, Published online: 17 Dec 2010
 

Abstract

The synthesis of new eight‐membered cycle dibenzo[b,f][1,5]‐diazocine‐6‐(5H)‐one derivatives 11, 12 was developed. The key step in this synthesis was the intramolecular cyclization of the amino aldehyde precursors 9,10 obtained by a selective reduction of the nitro benzamides 7, 8.

Acknowledgment

This work was supported by a grant from CEPEDEQ‐Facultad of the Chemical and Pharmaceutical Sciences Faculty, University of Chile, Santiago, Chile.

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