Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 32, 2002 - Issue 2
Journal homepage
256
Views
50
CrossRef citations to date
0
Altmetric
Original Articles

SYNTHESIS AND CHARACTERISATION OF RUTHENIUM(III) COMPLEXES CONTAINING MONOBASIC BIDENTATE SCHIFF BASES AND THEIR BIOLOGICAL ACTIVITIES

T. Daniel Thangadurai Department of Chemistry, Bharathiar University, Coimbatore, 641 046, India
,
M. Gowri Department of Chemistry, Bharathiar University, Coimbatore, 641 046, India
&
K. Natarajan Department of Chemistry, Bharathiar University, Coimbatore, 641 046, IndiaCorrespondence[email protected]
Pages 329-343 | Received 30 Apr 2001, Accepted 21 Nov 2001, Published online: 15 Feb 2007
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

ABSTRACT

New hexa-coordinated ruthenium(III) complexes of the type [RuX2 F(L)(EPh3)2] (X=Cl or Br; L=monobasic bidentate Schiff base ligand; E=P or As) have been synthesised by the reactions of [RuCl3(PPh3)3], [RuCl3(AsPh3)3], [RuBr3-(AsPh3)3] or [RuBr3(PPh3)2(MeOH)] with the appropriate ligands such as anthranilic acid cinnamaldehyde (Hanthcin), anthranilic acid p-tolualdehyde (Hanth-p-tol) and anthranilic acid p-anisaldehyde (Hanth-p-ans). All of these new complexes were characterised using various physico-chemical methods such as elemental analyses, spectral (IR, electronic and EPR), magnetic moment and cyclic voltammetric data. The antibacterial activities of ligands and their complexes have also been determined. An octahedral structure has been tentatively assigned to all of the new complexes.

Acknowledgments

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

Inner Complex Chelates. I. Analogs of Bisacetylacetoneethylenediimine and its Metal Chelates1,2
Source: American Chemical Society (ACS)
Mixed ligand complexes of ruthenium(II) containing α,β-unsaturated-β-ketoaminesand their antibacterial activity
Source: Springer Science and Business Media LLC
Synthesis and spectral and electrochemical properties of di-2-pyridyl ketone complexes of ruthenium and their reactions
Source: American Chemical Society (ACS)
Comparison of the [M(IV)(RR'dtc)3]+M(III)(RR'dtc)3 and [M(IV)(Et2dsc)3]+/M(III)(Et2dsc)3 (M = cobalt, rhodium, iridium; dtc = dithiocarbamate; dsc = diselenocarbamate) redox couples and the reactivity of the oxidation state (IV) complexes in solution and in the gas phase as studied by electrochemical and mass spectrometric techniques
Source: American Chemical Society (ACS)
Effect of the formation of silver nano‐binuclear complex on the refinement of cytotoxic and antibacterial potency of coumarin Schiff base: Spectroscopy, thermal, X‐ray diffraction analyses and density functional theory calculations
Source: Wiley
(E)-1-(4-Chloro-benzyl-idene)thio-semi-carbazide.
Source: (:unav)
Mixed-ligand complexes of ruthenium(II)- and osmium(II)-2-(arylazo)pyridines with one 2,2′-bipyrazine/2,2′-bipyrimidine: synthesis, spectra and electrochemistry
Source: Elsevier BV
Microwave-assisted synthesis, characterization, and antimicrobial activity of some odorant Schiff bases derived from naturally occurring carbonyl compounds and anthranilic acid
Source: Informa UK Limited
New complexes of ruthenium (II) and (III) with triphenylphosphine, triphenylarsine, trichlorostannate, pyridine and other ligands
Source: Elsevier BV
New ruthenium(III) complexes containing tetradentate Schiff bases and their antibacterial activity
Source: Springer Science and Business Media LLC
Synthesis, Spectra and Electrochemistry of Ru(III) Complexes with Tetradentate Schiff Bases
Source: Informa UK Limited
Synthesis and Characterisation of Ruthenium(III) Complexes Containing Triphenylphosphine/Arsine and Schiff Bases
Source: Informa UK Limited
Synthesis, characterization, and EPR studies of stable ruthenium(III) Schiff base chloro and carbonyl complexes
Source: American Chemical Society (ACS)
Stereochemistry and antifungal activity of complexes of 2-(O-hydroxybenzylidene) amino-5-phenyl-1,3,4-oxadiazole with some first transition series metal ions
Source: Elsevier BV
Synthesis, characterization and biocidal studies of ruthenium(II) carbonyl complexes containing tetradentate Schiff bases
Source: Springer Science and Business Media LLC
Ruthenium(III) Complexes with β-Diketones Containing Triphenylphosphine and Triphenylarsine
Source: Informa UK Limited
Complexes of osmium, ruthenium, rhenium, and iridium halides with some tertiary monophosphines and monoarsines
Source: Royal Society of Chemistry (RSC)
Mixed Ligand Complexes of Ruthenium(III) Containing α, β -Unsaturated-β-Ketoamine and Triphenylphosphine/Arsine
Source: Informa UK Limited
Triphenylphosphine and Triphenylarsine Complexes of Ruthenium(III) Containing Dithiocarbazate Schiff Bases
Source: Informa UK Limited
Preparation and properties of rare earth element complexes with pyridine-2,6-dicarboxylic acid
Source: Elsevier BV
2′-Hydroxychalconate Complexes of Ru(III) Containing Triphenylphosphine or Triphenylarsine
Source: Informa UK Limited
Mixed complexes of ruthenium(III) and ruthenium(II) with triphenylphosphine or triphenylarsine and other ligands
Source: Elsevier BV
Novel Cr (III), Fe (III) and Ru (III) Vanillin Based Metallo‐Pharmaceuticals for Cancer and Inflammation Treatment: Experimental and Theoretical Studies
Source: Wiley
Synthesis and antioxidant activity of some new coumarinyl-1,3-thiazolidine-4-ones.
Source: MDPI AG

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.