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Original Articles

Chelating Behavior of 14‐Membered Schiff Base Macrocycles and Their Transition Metal Chelates

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Pages 145-161 | Received 15 Feb 2002, Accepted 05 Sep 2003, Published online: 16 Nov 2010
 

Abstract

The new Schiff base 14‐membered macrocycles, 1,5,8,12‐tetraazacyclotetradeca‐6,7,13,14‐tetraaminoacetic acid‐5,7,12,14‐tetraene (L1), 1,5,8,12‐tetraazacyclotetradeca‐6,7,13,14‐tetraaminophenyl‐5,7,12,14‐tetraene (L2) and 1,5,8,12‐tetraazacyclotetradeca‐6,7,13,14‐tetraaminopyridyl‐5,7,12,14‐tetraene (L3), have been synthesized by the reaction of N,N‐dicarboxymethyloxamide, N,N‐diphenyloxamide or N,N‐dipyridyloxamide with 1,3‐diaminopropane. Their complexes with Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) ions have been prepared and characterized by elemental analyses, IR, 1H NMR and electronic spectra, magnetic moment and conductivity measurements. The complexes of the divalent metal ions are non‐ionic while those of the trivalent metal ions appear to be 1:1 electrolytes. On the basis of these studies an octahedral geometry is proposed for all of the complexes.

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