Advanced search
Publication Cover
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 34, 2004 - Issue 2
Journal homepage
85
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

Hydrothermal Synthesis, Crystal Structure, and Properties of Nickel(II) Coordination Polymer with 2,2′‐Bipyridyl‐3,3′‐dicarboxylate

Ben‐lai Wu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
,
Hong‐quan Zhang College of Medicine, Zhengzhou University, Zhengzhou, P. R. China
,
Hong‐yun Zhang Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. ChinaCorrespondence[email protected]
,
Qing‐an Wu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
,
Hong‐wei Hou Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
,
Yu Zhu Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
&
Xiang‐yu Wang Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, P. R. China
 show all
Pages 313-321 | Received 08 Oct 2002, Accepted 07 Oct 2003, Published online: 16 Nov 2010
 
Sample our Engineering & Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days

Abstract

The polymeric complex [Ni(bpdc)(H2O)2] n (bpdc, 2,2′‐bipyridyl‐3,3′‐dicarboxylate dianion) which consist of [Ni(bpdc)(H2O)2] units was synthesized using a hydrothermal method. Its crystal structure was determined by x‐ray crystal diffraction as 1‐D chain‐like polymer. In [Ni(bpdc)(H2O)2] n , each bpdc bridges a Ni(II) pair in a unique tetradentate fashion through its two pyridine nitrogen atoms and two oxygen atoms of two carboxyl groups. Each Ni(II) cation has a slightly distorted octahedral coordination environment where the equatorial plane includes the two nitrogen atoms of one bpdc ligand and two oxygen atoms of another bpdc anion, while the axial positions are occupied by two oxygen atoms of two coordinated water molecules. In the polymeric complex the complicated hydrogen‐bonding network and π–π stacking interaction play an important role for its thermostability.

Acknowledgments

This work was supported by the Natural Science Foundation of Henan Education Department (20011500001) and the Natural Science Foundation of Henan Province (0211020300).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

A Three-Center Hydrogen Bond in 2,6-Diphenylpyridinium Tetrachloroaurate
Source: American Chemical Society (ACS)
Allosteric manipulation of photoexcited state relaxation in (bpy)2RuII(binicotinic acid).
Source: (:unav)
Hydrothermal synthesis and characterization of a zigzag neodymium-2,2′-bipyridine-3,3′-dicarboxylate-isonicotinate coordination polymer
Source: Informa UK Limited
Network structures with 2,2′-bipyridine-3,3′diol: a discrete Co(III) complex that forms a porous 3-D hydrogen bonded network, and Cu(II) coordination chains
Source: (:unav)
Synthesis and Crystal Structure of a Novel One-Dimensional Coordination Chain: [Ag(μ3-Hbpyca)(H2O)]n (bpyca = 2,2'-Bipyridine-3,3'-dicarboxylate)
Source: (:unav)
A Unique μ‐dichloro‐Bridged Butterfly‐shaped Dimer: Synthesis and Crystal Structure of [Cu(bpmh)Cl2]2 (bpmh=2,2′‐bipyridyl‐3‐carbomethoxy‐3′‐formylhydrazine), Roles of π–π Interaction and Steric Hindrance Effect in Crystal Packing
Source: (:unav)
Spectroscopic and electrochemical properties of ruthenium(II) polypyridyl complexes
Source: Royal Society of Chemistry (RSC)
CCDC 191288: Experimental Crystal Structure Determination
Source: Cambridge Crystallographic Data Centre
3,3′-Dicarbomethoxy-2,2′-bipyridyl complexes of palladium(II), platinum(II) and rhodium(III)
Source: Elsevier BV
Crystal structure and properties of a polymeric chain copper(II) complex [Cu(bpc)(H2O)2] (bpc = 2,2′-bipyridyl-3,3′-dicarboxylate)
Source: Elsevier BV
Molecular interactions in substituted 2,2′-bipyridines: crystal structures of 2,2′-bipyridine-3,3′-dicarboxylic acid monohydrate and (2,2′-bipyridine-3,3′-dicarboxylic acid)dichlorocopper(II) dihydrate
Source: Springer Science and Business Media LLC
Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2·H2O (bp3ca = 2,2‘-Bipyridine-3,3‘-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges
Source: American Chemical Society (ACS)
Crystal structure of catena -poly [tetraaqua(2,2'-bipyridine-3,3'-dicarboxylato)Mn(II)]
Source: Walter de Gruyter GmbH
Synthesis, structure, and characterization of a silver(I) coordination polymer with μ6-bridging 2,2′-bipyridyl-3,3′-dicarboxylate
Source: (:unav)

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.