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Original Articles

Metal Complexes: Preparation, Magnetic, Spectral, and Biocidal Studies of Some Mixed‐Ligand Complexes with Schiff Bases Containing NO and NN Donor Atoms

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Pages 553-563 | Received 08 Jul 2003, Accepted 01 Dec 2003, Published online: 16 Nov 2010
 

Abstract

Metal complexes of the types [M(SB1)2acphen] and [M(SB2)2acphen] where M = Mn(II), Co(II), Ni(II), Cu(II), and Cd(II); HSB1 = 5‐chlorosalicylidene‐p‐anisidine and HSB2 = 5‐bromosalicylidene‐p‐anisidine have been prepared and characterized. Magnetic susceptibility measurements, elemental analyses, electro‐nic, and infrared spectral data suggest six‐coordinated octahedral structures for these complexes. The mixed‐ligand complexes show higher activity against Sacch aromyces cereuisae, Salmonella typhi, Fasarium oxysporum, and Lasiodiplodia theobromae as compared to the ligand, metal salts, and control.

Acknowledgments

The authors are thankful to the Head, Department of Chemistry, and Head, Department of Bio‐Sciences, Sardar Patel University, Vallabh Vidyanagar, India, for providing the necessary laboratory facilities.

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