Reaction of Sn(II) Adduct with MCl₂ [M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)]

K. S. Siddiqi Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, U.P., IndiaCorrespondence[email protected]

Hina Afaq Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, U.P., India

Ahmad Umar Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, U.P., India

Shahab A. A. Nami Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, U.P., India

R. J. Singh Department of Physics, Aligarh Muslim University, Aligarh, U.P., India

Abstract

Complexes of SnCl₂ · py with MCl₂, where M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II), have been prepared and characterized by the elemental analysis, TGA, DTA, EPR, and IR spectra. All the compounds prepared are stable at room temperature but they are hygroscopic in nature. Substitution reactions of SnCl₂ · py(MCl₂) by dithiocarbamate afforded (SnCl₂ · py)₂M(dtc)₂. An octahedral geometry for the metal dithiocarbamates has been proposed.

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Acknowledgment

Two of the authors (SAAN and AU) thank the CSIR, New Delhi for financial assistance through grant No. 01(1783)/02/EMR‐II.

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Reaction of Sn(II) Adduct with MCl2 [M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)]

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Reaction of Sn(II) Adduct with MCl₂ [M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)]