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In this study, dipositive platinum(II) complexes of the general formula [Pt(L–L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), and dppp (Ph2PCH2CH2CH2PPh2), have been synthesized and characterized by 31P{1H} NMR, 13C NMR, IR spectra and elemental analyses.
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