EFFECTS OF CHEMICAL IMPURITIES ON GAS SORPTION IN POLYMERIC MEMBRANES. II. PC-1 AND PC-2

Abstract

In recent years, polymeric membranes have been increasingly used in key unit operations such as gas separations. In theory, the performance of a polymeric membrane module depends solely on the chemical structure of the polymer and the feed gas composition. It has, however, been observed that impurities in the feed stream (such as vapors from compressor oils) affect the productivity of the membrane module even at parts per million (ppm) levels.

In order to understand the fundamental effects of such trace chemicals, commercial polymers were studied for their solubility and permeability characteristics in the presence and absence of such impurities. Solubilities of N₂, O₂, CH₄, and CO₂ were measured in dense homogeneous films at 35°C. Two types of compressor oils were used in doping the polymers at three concentration levels. Results from the solubility data were well described by the dual-mode model for glassy polymers that consists of a Henry's solubility term k_D , Langmuir sorption capacity C_H ′, and an affinity constant “b.” The effect of the oil on each of the model parameters is presented. The effect of annealing on sorption in clean and doped samples of the polymers was also examined. Such thermal treatment affected the Langmuir sorption capacity C_H ′ more than any of the other dual-mode parameters. Annealing lowered C_H ′ because of the ensuing densification of the glassy structure. This effect was common to both clean and doped films. A good understanding of the effects of such trace chemicals on gas solubility in synthetic membranes will assist in examining effects of impurities on the overall membrane productivity and aid in designing effective polymeric membrane modules in the future.

ACKNOWLEDGMENTS

We gratefully acknowledge the financial support provided by MG Generon, Pittsburg, California, and wish to thank Mr. Fred Coan and Mr. Tom Jeanes for their suggestions and help during the experimental phase of the project. We would also like to express our deep appreciation and gratitude to Mr. Tom Breese for his invaluable technical assistance throughout the entire course of this project. A special thanks to Dr. Roger Korus for the helpful suggestions offered during the preparation of this manuscript.