Methanol and acetaldehyde fluxes over ryegrass

Abstract

Oxygenated volatile organic compounds (OVOCs) play an active role in tropospheric chemistry but our knowledge concerning their release and ultimate fate is limited. However, the recent introduction of Proton Transfer Reaction Mass Spectrometry (PTRMS) has improved our capability to make direct field observations of OVOC mixing ratios and fluxes. We used PTRMS in an eddy covariance setup to measure selected OVOC exchange rates above a well-characterized agricultural plot in Northern Germany. In fall 2003, mixing ratios of methanol and acetaldehyde 2m above the field ranged from 1 to 10 and 0.4 to 2.1 ppb, respectively, well correlated with one another. Fluxes of both gases were followed for growing Italian ryegrass (Lolium multiflorum) over a significant portion of its life cycle. Diurnally fluctuating emissions of methanol and very small acetaldehyde fluxes were observed up to the cutting and removal of the grass. Methanol emissions were exponentially related to ambient temperatures and appeared to be higher during the grass’ rapid leaf area expansion and after a rain event. Acetaldehyde exchanges averaged over the whole period indicated very slow deposition. Our measurements confirm previous, similar results, as well as presumptions that grasses are comparatively low methanol emitters compared to non-grass species.