Effect of viscosity ratio of the components of thermoplastic and liquid-crystalline polymer blends on the properties

Abstract

The effects of viscosity ratio on the rheological and mechanical properties of the blends of four thermoplastics of low viscosity and a liquid crystalline polymer (LCP) were studied. A polyamide of reduced crystallinity (amorphous PA), a polycarbonate (PC), a polyethylene-terephthalate (PET), and a cyclic polyolefin (COC) were investigated with the copolymer of 2-hydroxy-6-naphthoic acid (HNA) and 4-hydroxybenzoic acid (HBA) (Vectra A type LCP). The LCP content changed in the range of 0–50 w/w%. The mechanical properties were determined by tensile tests on injection molded test bars in parallel and perpendicular directions to the flow. Except for the PC/LCP blends, the viscosity decreased with increasing LCP content, the tensile strength increased significantly in the parallel and decreased in the perpendicular direction indicating formation of fibrillar phase morphology. In the case of PC/LCP blends, a reinforcing effect was observed at low LCP contents, but above 20 w/w% the viscosity increased and the parallel tensile strength dropped to the value measured in the perpendicular direction. The loss of the reinforcing effect might originate from chemical reactions of the two polymers.

Keywords:

• LIQUID-CRYSTALLINE POLYMER BLENDS
• VISCOSITY RATIO
• POLYCARBONATE
• POLYETHYLENE-TEREPHTHALATE
• CYCLIC POLYOLEFIN
• AMORPHOUS POLYAMIDE