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Abstract
This paper aims to study the sintering of 316L stainless steel and alumina composites. Compositions range from 0 to 100 vol.-% steel, and the experimental procedures involve density and microstructure analysis of the samples, as well as dilatometric measurements. In this study, it is shown that reducing atmosphere debinding can lead to carbon residues. These have a negative effect on alumina densification by delaying the sintering onset. For metal–ceramic composites, densification is modified by a complex interaction involving carbon (which lowers alumina density), chromium oxide (which is documented in literature to diminish alumina densification) and stainless steel phase. Chromium carbide formation is possible for some experimental conditions (1–30% stainless steel and hydrogenated argon debinding); this mechanism, locking both carbon and chromium outside alumina phase, leads to higher sintered densities.
This work is based on a running project supported by the Funds of Competitiveness of Companies and the Viameca pole of competitiveness.