Abstract
Nitrocarburising is a thermochemical diffusion treatment involving the surface nitrogen enrichment of low alloyed steels, leading to the formation of iron carbonitrides characterised by good tribological properties. In order to make engineering components multi-functional, new processes including post-operations have been developed in the last decade but their influence on corrosion resistance is not yet fully understood. The aim of the present study is to determine the corrosion behaviour of gas nitrocarburised steel produced on both a laboratory and industrial scale. Behaviour has been evaluated by salt spray tests as well as by electrochemical techniques (corrosion potential and polarisation resistance evolutions versus immersion time, potentiodynamic curves). All nitrocarburising treatment improves the corrosion resistance compared to untreated steel. Post-oxidising treatments have no significant influence on corrosion resistance but an impregnation step appears efficient in enhancing corrosion. The carbonitrides present in the 'white layer' are nobler than the substrate, and promote localised corrosion through open porosity of the outlayer by a galvanic effect.