Abstract
The present paper reports the electrical properties of undoped TiO2 single crystal in terms of the conductivity components for electrons, holes and ions and the related transference numbers within the n–p transition regime. These data indicate that ionic conductivity in TiO2 may assume a substantial value, which cannot be ignored. The minimum of the electrical conductivity at the n–p transition and its electronic component, were used for the determination of the band gap, which is 3·13 and 3·1 eV respectively.