Correlation between properties of zirconia mullite and Y₂O₃ stabilised zirconia mullite derived by various processing techniques

Abstract

Abstract

Zirconia mullite (MUZ) and Y₂O₃–MUZ composites were synthesised by plasma melting, plasma sintering and conventional sintering techniques. Mixtures of tetragonal and cubic phases have been observed in all the processed Y₂O₃–MUZ composites. This observation infers that though the available temperature in plasma sintered and conventionally sintered MUZ specimens is not sufficient for the transformation of monoclinic to cubic zirconia, the addition of Y₂O₃ favours this transformation and also stabilises the cubic zirconia phase at room temperature. The optical absorption studies completely reflect the improvement in optical band gap of Y₂O₃–MUZ composites to prove it as a suitable candidate for refractory applications. The bulk density, hardness and higher crystalline nature of plasma sintered composites indicate that better quality of products can be synthesised by direct current extended arc thermal plasma heating technique within a short duration of time.

Keywords:

• Zirconia mullite
• Melting
• Sintering
• Raman spectroscopy
• Refractories
• Yttria stabilised zirconia

The authors are grateful to the Director of IMMT (CSIR)-Bhubaneswar for providing research support.