Characterisation of transparent hydroxyapatite nanoceramics prepared by spark plasma sintering

Abstract

Hydroxyapatites (HA) have good biocompatibility and are used as bioceramics for artificial bones. The application areas can be extended further if transparent and dense HA ceramics can be prepared. The preparation of dense and transparent HA ceramics were attempted using a spark plasma sintering technique at relatively low temperatures (900–1000°C) under a pressure of 80 MPa for a short time of 10 min. The sintered body was almost fully dense (>99%) and transparent with a transmittance >70%. The microstructure was examined by SEM, TEM, STEM and EDX. The HA ceramics exhibited a microstructure with grains, approximately 100 nm size. A number of intragranular voids, 5–10 nm in size, with flat boundaries were also observed. The voids were believed to have been generated by evaporation during spark plasma sintering and were stabilised during cooling. The grain boundaries were clean without a glassy phase.

Keywords:

• Transparent ceramics
• Hydroxyapatite nanoceramics
• Spark plasma sintering
• Electron microscopy

Acknowledgements

The authors are grateful to technical assistance of Mr Changhun Hwang at Kyungnam University, and Dr Jungho Yoo at National Nanofab Center, Korea.