Abstract
A Ti–6Al–4V/σ (SM 1240) composite prepared by diffusion bonding has been studied in the as received condition, using Auger electron spectroscopy, transmission electron energy loss spectroscopy, and scanning electron microscopy. The SiC based σ fibre has a tungsten core, and a duplex coating of carbon (adjacent to the SiC deposit) and TiBx. It is shown that boron from the TiBx layer diffused into the matrix and formed TiB needles. Carbon was detected in the TiBx layer and was present in elemental free form. A continuous SiO2+ carbon layer was detected at the SiC/carbon layer interface. Analysis of in situ fracture composite surfaces in an Auger spectrometer has shown that the tensile failure was initiated within the carbon layer or at the TiBx/matrix interface. An oxide layer detected at the TiBx/matrix interface influenced the fracture behaviour of the composite.
MST/2027