Lipase-catalyzed Kinetic Resolution of (±)-cis,cis-Spiro[4.4]nonane-1,6-diol

Yoshitaka MATSUSHIMADepartment of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo

Takeshi KITAHARADepartment of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo

Kenji MORIDepartment of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo

Abstract

(±)-cis,cis-Spiro[4.4]nonane-1,6-diol (1), which has axial chirality, was efficiently resolved by lipase-catalyzed enantioselective esterification in diisopropyl ether.

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Lipase-catalyzed Kinetic Resolution of (±)-cis,cis-Spiro[4.4]nonane-1,6-diol

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Lipase-catalyzed Kinetic Resolution of (±)-cis,cis-Spiro[4.4]nonane-1,6-diol

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