Enantioselective Synthesis of Both the Enantiomers of Jasmine Ketolactone and Its Epimer

Munenori INOUEDepartment of Applied Biological Chemistry, Graduate School of Agricultural and Biological Sciences, The University of Tokyo

Tsunehiro NISHIDepartment of Applied Biological Chemistry, Graduate School of Agricultural and Biological Sciences, The University of Tokyo

Takeshi KITAHARADepartment of Applied Biological Chemistry, Graduate School of Agricultural and Biological Sciences, The University of Tokyo

Abstract

The enantioselective synthesis of jasmine ketolactone 1, which was isolated as a component of Italian jasmine oil, and its epimer 2 is described. Lactones 1 and 2 were synthesized in 5 and 4 steps, respectively, by Yamaguchi’s macrolactonization method from alcohol 4.

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Enantioselective Synthesis of Both the Enantiomers of Jasmine Ketolactone and Its Epimer

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Enantioselective Synthesis of Both the Enantiomers of Jasmine Ketolactone and Its Epimer

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